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If you are getting an option to enter the password, then you should log in using the username and password you have created for RefWorks. If you haven't yet created an account you can do that by selecting the "Sign Up for a New Account" link at the top of the login box.
The group code will only be used from off campus. It will be asked for in a single box, without requesting a password. After entering the group code you will still need to log in using the user name and password you created.